Gabriel Canard

Localisation

TPR1 - 5 étage

Grade

PU2

Function

enseignant - chercheur

Room

G.05.16

canard.jpg

Activity

Chimie supramoléculaire, systèmes pi-conjugués, électrochimie

Themes

1) Syntheses and applications of corroles, porphyrins and other porphyrinoids 

2) Covalent and non-covalent multichromophoric assemblies

3) Electrochemistry

4) Syntheses and characterizations of benzoquinone mono-, and diimines, of azacalixarenes and of azacalixphyrins

Parcours

Dr. Gabriel Canard is Full Professor at Aix-Marseille University.

He carried his undergraduate and graduate studies in chemistry at the University of Burgundy (Dijon, France) where he completed his Ph.D thesis in 2004 with the supervision of Dr. Jean-Michel Barbe in the group of Pr. Roger Guilard. His Ph.D thesis was dealing with the selective adsorption of carbon monoxide by hybrid organic-inorganic materials incorporating cobalt(III) corroles.

In january 2005, he moved to the University of Geneva (Switzerland) to work as a postdoctoral research fellow in the group of Prof. Claude Piguet, where he developed various helicates incorporating lanthanide ions to investigate the contribution of various thermodynamic parameters in the stabilities of polymetallic complexes.

In september 2007, he was recruited as a Maître de Conférences (Assistant Professor) at the Institut Universitaire de Technologie (IUT) of Aix-Marseille University where he teaches chemistry to undergraduate students. His research was conducted in the group of Pr. Teodor Silviu Balaban and was dealing with the syntheses, functionalizations and self-assemblies of porphyrin derivatives and of their contracted homologues corroles.

In October 2012, he joined the group of Dr. Olivier Siri at the CINaM where besides his research interest on porphyrinoids, he is involved in the main group research topics on the synthesis and developments of azacalixarenes and benzoquinone-diimines derivatives. Dr. Gabriel Canard received his "Habilitation à Diriger des Recherches" (Associate Professor position) in december 2017.

In September 2022, he became full professor at Aix-Marseille University.

Publications

2024

Controlled Reactivity of Viologens in Alkaline Solutions Via Cucurbit[7]uril Complexation

Axel Bossavit, Valérie Monnier, Didier Siri, Gabriel Canard, Didier Gigmes, David Bardelang, Anthony Kermagoret

European Journal of Organic Chemistry 27:e202400404 (2024)10.1002/ejoc.202400404

Two-step access to bis- meso -perfluoroalkyl-corroles towards meso -perfluoroacyl-ABC-corroles

Paul-Gabriel Julliard, Simon Pascal, Olivier Siri, Michel Giorgi, Diego Cortés-Arriagada, Luis Sanhueza, Gabriel Canard

Organic & Biomolecular Chemistry (2024)10.1039/D4OB00191E

Feasibility of Multiple Excited-State Proton Transfer Processes in Hydroxyquinoline-containing Benzobisimidazole Dyes

Tatiana Munteanu, Dancho Yordanov, Gabriel Canard, Olivier Siri, Denis Jacquemin, Anton Georgiev, Simon Pascal

New Journal of Chemistry 48:13289-13295 (2024)10.1039/D4NJ01787K

Post-functionalization of triamino-phenazinium dyes to reach near-infrared emission

Tatiana Munteanu, Jean-François Longevial, Gabriel Canard, Denis Jacquemin, Simon Pascal, Olivier Siri

RSC Advances 14:19257-19263 (2024)10.1039/D4RA03245D

High-Order Commensurate Zwitterionic Quinonoid Phase Induces a Nanoscale Dipole Lattice on Graphene

Gaelle Nassar, Diego Cortés-Arriagada, Luis Sanhueza-Vega, Périne Landois, Matthieu Paillet, Haitham Hrich, Sylvie Contreras, Olivier Siri, Simon Pascal, Laurence Masson, Conrad Becker, Alain Ranguis, Romain Parret, Gabriel Canard, Thomas Leoni

Journal of Physical Chemistry C 128:9712-9721 (2024)10.1021/acs.jpcc.4c01695

Electrocatalytic Properties of meso ‐ Perfluorinated Metallo Corroles for the Reduction of CO 2

Chanjuan Zhang, Paul‐gabriel Julliard, Diana Dragoe, Ally Aukauloo, Gabriel Canard

European Journal of Inorganic Chemistry 27:e202400318 (2024)10.1002/ejic.202400318

2023

Azacalixphyrin nanostructures

Daniel Ferry, Sabrina Pricl, Domenico Marson, Zhongrui Chen, Gabriel Canard, Simon Pascal, Aura Tintaru, Olivier Siri

Journal of Porphyrins and Phthalocyanines 27:1231-1240 (2023)10.1142/S1088424623500785

Core–Shell Multiwalled Carbon Nanotube/Cobalt Corrole Hybrids for the Oxygen Reduction Reaction

Paul-Gabriel Julliard, Manel Hanana, Laurent Alvarez, Renaud Cornut, Bruno Jousselme, Gabriel Canard, Stéphane Campidelli

Energy & Fuels 37:684-692 (2023)10.1021/acs.energyfuels.2c03434

Proton-coupled electron transfer in a pivaloyl-substituted dihydro-tetraazapentacene

Jean-François Longevial, Iryna Knysh, Shaymaa Al Shehimy, Lhoussain Khrouz, Arumugam Pandurangan, Simon Pascal, Gabriel Canard, Christophe Bucher, Denis Jacquemin, Olivier Siri

Electrochimica Acta 449:142224 (2023)10.1016/j.electacta.2023.142224

A Strategy to Design Substituted Tetraamino-Phenazine Dyes and Access to an NIR-Absorbing Benzoquinonediimine-Fused Quinoxaline

Tatiana Munteanu, Valérie Mazan, Mourad Elhabiri, Camil Benbouziyane, Gabriel Canard, Denis Jacquemin, Olivier Siri, Simon Pascal

Organic Letters 25:3886-3891 (2023)10.1021/acs.orglett.3c01251

Deciphering electronic and structural effects in Copper Corrole/Graphene Hybrids

Kerry Wrighton-Araneda, Diego Cortés-Arriagada, Paulina Dreyse, Simon Pascal, Gabriel Canard, Luis Sanhueza

Chemistry - A European Journal 29:e202203175 (2023)10.1002/chem.202203175

Breaking Azacalix[4]arenes into Induline Derivatives

Chen Zhongrui, Gabriel Canard, Grauby Olivier, Benjamin Mourot, Olivier Siri

Molecules 28 (2023)10.3390/molecules28248113

2022

Fully Zwitterionic Diaminobenzoquinonediimines Promoted by Cyanoaromatic N-substituents

Tereza Horáčková, Manon H.E. Bousquet, Adrien Morice, Ugo Triballier, Gabriel Canard, Pavel Lhoták, Denis Jacquemin, Simon Pascal, Olivier Siri

Dyes and Pigments (2022)10.1016/j.dyepig.2022.110681

Synthesis and Electron Accepting Properties of Two Di(benz[f]indenone)-Fused Tetraazaanthracene Isomers

Bruno Salgues, Rudraditya Sarkar, Muhammad Fajri, Yatzil Avalos-Quiroz, Anne-Doriane Manick, Michel Giorgi, Nicolas Vanthuyne, Yannick Carissan, Christine Videlot-Ackermann, Jörg Ackermann, Gabriel Canard, Jean-Luc Parrain, Boris Le Guennic, Denis Jacquemin, Muriel Amatore, Laurent Commeiras, Elena Zaborova, Fréderic Fagès

Journal of Organic Chemistry 87:3276-3285 (2022)10.1021/acs.joc.1c02942

Optoelectronic properties of a self-assembling rigidly-linked BF2-curcuminoid bichromophore

Claire Tonnelé, Manon Catherin, Michel Giorgi, Gabriel Canard, David Casanova, Frédéric Castet, Elena Zaborova, Frédéric Fages

Dyes and Pigments 207:110677 (2022)10.1016/j.dyepig.2022.110677

2021

Effect of the electron donating group on the excited-state electronic nature and epsilon-near-zero properties of curcuminoid-borondifluoride dyes

Kyu-Ri Choi, Dae Hyeon Kim, Yeon Ui Lee, Virginie Placide, Steven Huynh, Dandan Yao, Gabriel Canard, Elena Zaborova, Fabrice Mathevet, Loïc Mager, Benoît Heinrich, Jean-Charles Ribierre, Weon Jeong, Frédéric Fages, Anthony d'Aléo

RSC Advances 11:38247-38257 (2021)10.1039/d1ra08025c

Functionalized porphyrins from meso-poly-halogeno-alkyl-dipyrromethanes: synthesis and characterization

Paul-Gabriel Julliard, Simon Pascal, Olivier Siri, Diego Cortés-Arriagada, Luis Sanhueza, G. Canard

Comptes Rendus. Chimie 24:1-19 (2021)10.5802/crchim.97

Switching from Single to Simultaneous Free-Radical and Anionic Polymerization with Enamine-Based Organic Electron Donors

Yuxi Zhao, Marion Rollet, Laurence Charles, Gabriel Canard, Didier Gigmes, Patrice Vanelle, Julie Broggi Broggi

Angewandte Chemie International Edition 60:19389-19396 (2021)10.1002/anie.202106733

2020

Exciton Interactions, Excimer Formation, and [2π+2π] Photodimerization in Nonconjugated Curcuminoid‐BF 2 Dimers

Manon Catherin, Olatz F Uranga-Barandiaran, Arnaud Brosseau, Rémi Métivier, Gabriel Canard, Anthony d'Aléo, David Casanova, Frederic Castet, Elena Zaborova, Frédéric Fages

Chemistry - A European Journal 26:3818-3828 (2020)10.1002/chem.201905122

Mixed N-Aryl/Alkyl Substitution Favours an Unusual Tautomer of Near-Infrared Absorbing Azacalixphyrins

Lucien Lavaud, Cloé Azarias, Gabriel Canard, Simon Pascal, Denis Jacquemin, Olivier Siri

New Journal of Chemistry (2020)10.1039/D0NJ04587J

Stabilization of a 12-π electrons diamino-benzoquinonediimine tautomer

Jean-François Longevial, Zhongrui Chen, Simon Pascal, Gabriel Canard, Denis Jacquemin, Olivier Siri

Chemical Communications (2020)10.1039/D0CC06815B

Small Panchromatic and NIR Absorbers from Quinoid Zwitterions

Angélina Torres Ruiz, Manon Bousquet, Simon Pascal, Gabriel Canard, Valérie Mazan, Mourad Elhabiri, Denis Jacquemin, Olivier Siri

Organic Letters (2020)10.1021/acs.orglett.0c02926

2019

Versatile transamination in quinonediimine chemistry: Towards a novel class of water soluble UV/violet chromophores

Zhongrui Chen, Maxime Bert, Simon Pascal, Gabriel Canard, Olivier Siri

Tetrahedron Letters 151024 (2019)10.1016/j.tetlet.2019.151024

Fused Bis-Azacalixphyrin that reaches NIR II absorptions

Lucien Lavaud, Cloe Azarias, Gabriel Canard, Simon Pascal, Joachim Galiana, Michel Giorgi, Zhongrui Chen, Denis Jacquemin, Olivier Siri

Chemical Communications (2019)10.1039/C9CC09021E

Azacalixquinarenes: From Canonical to (Poly-)Zwitterionic Macrocycles

Simon Pascal, Lucien Lavaud, Cloé Azarias, Alexandre Varlot, Gabriel Canard, Michel Giorgi, Denis Jacquemin, Olivier Siri

Journal of Organic Chemistry 84:1387-1397 (2019)10.1021/acs.joc.8b02847

2018

Meso-Ester Corroles

Gabriel Canard, Di Gao, Anthony d'Aléo, Michel Giorgi, Florian-Xuan Dang, Teodor Silviu Balaban

Chemistry - A European Journal (2018)

Regioselective addition of DDQ on a quinoid ring: an entry into chiral zwitterionic bridging ligands

Gabriel Canard, Zhongrui Chen, Aprilliyani Suryaningtias, Marion Jean, Nicolas Vanthuyne, Michel Giorgi, Christian Roussel, Olivier Siri

New Journal of Chemistry 42:8247-8252 (2018)10.1039/c7nj03765a

Azacalixphyrins as NIR photoacoustic contrast agents

Lucien Lavaud, Simon Pascal, Khaled Metwally, Damien Gasteau, Anabela da Silva, Zhongrui Chen, Mourad Elhabiri, Gabriel Canard, Denis Jacquemin, Olivier Siri

Chemical Communications 54:12365-12368 (2018)10.1039/C8CC05851B

Controlling the canonical/zwitterionic balance through intramolecular proton transfer: a strategy for vapochromism

Simon Pascal, Lucien Lavaud, Cloé Azarias, Gabriel Canard, Michel Giorgi, Denis Jacquemin, Olivier Siri

Materials Chemistry Frontiers 2:1618-1625 (2018)10.1039/C8QM00171E

Near-Infrared Electroluminescence and Low Threshold Amplified Spontaneous Emission above 800 nm from a Thermally Activated Delayed Fluorescent Emitter

Hao Ye, Dae Hyeon Kim, Xiankai Chen, Atula Sandanayaka, Jong Uk Kim, Elena Zaborova, Gabriel Canard, Youichi Tsuchiya, Eun Young Choi, Jeong Weon Wu, Frédéric Fages, Jean-Luc Brédas, Anthony D’aléo, Jean-Charles Ribierre, Chihaya Adachi

Chemistry of Materials 30:6702-6710 (2018)10.1021/acs.chemmater.8b02247