Clemens Barth

Axe

Nanomatériaux

E-mail

barth@cinam.univ-mrs.fr

Phone

+33(0)6 60 36 28 19

Fax

+33(0)4 91 41 89 16

Localisation

R2

Grade

CRCN

Fonction

chercheur

barth.jpg

Activité

Heterogeneous catalysis, oxide surfaces, metal nanoparticles, molecular self-assembly of molecules, noncontact AFM (nc-AFM), Kelvin probe force microscopy (KPFM)

Recherche

My other pages are here!

I am chargé de recherche (permanent researcher) in the French CNRS (Institut de Physique, Section 05, condensed matter) and work in the CINaM institut, which is located on the Campus of Luminy in Marseille, in the south part of France. My work deals with the fundamental research of insulating ionic surfaces (oxide surfaces, bulk ionic crystal surfaces, thin insulating ionic films on metal surfaces) and of supported metal nanoparticles (NPs) and small functionalized molecules, which I characterzie by noncontact atomic force microscopy (nc-AFM) and Kelvin probe force microscopy (KPFM). Some of my results are summarized in a recent review (Advanced Materials 23 (2011) 477). The main keywords are:

Surfaces

    - Atomic surface structure
    - Surface defects
    - Surface reconstruction
    - Dopage, influence of impurities (e.g. surface double layer or Debye-Frenkel layer)
    - Large defect systems, precipitation and new phase creation (e.g. Suzuki phase)
    - Nanostructuration

Metal nanoparticles (NPs)

    - Growth, nucleation, sintering, morphology, structure
    - Work function
    - Charge and polarization related phenomena
    - Adsorption and contamination of species at NPs (carbon)

Molecules

    - Functionalized molecules
    - Thin molecular films
    - Adsorption/desorption, charge matching
    - Supramolecular self-assembly, pi-pi stacking

Heterogeneous model catalysis. A large part of my research is located in heterogeneous model catalysis. In particular, I focus on the morphology, atomic structure, defects and charge state of oxide surfaces (MgO, Al2O3 and since recently also ceria). Furthermore, I characterize supported gold (AuNPs) and palladium nanoparticles (PdNPs), their morphology and structure but also charge related phenomena. Recently, I started to 'visualize' the reactivity of metal NPs by using the Kelvin microscope and monitoring work function changes at NPs. For instance, we could observe strong WF changes upon carbon contamination at PdNPs. Although alkali halides are not relevant in heterogeneous catalysis, they are nevertheless very interesting for me because they are somewhat similar to oxide surfaces. One advantage by using alkali halide surfaces is that they are accessible for high resoultion nc-AFM and KPFM imaging. Furthermore, because the type of surface defects can be narrowed down to only a few the identification of defects is relatively easy to accomplish. For instance, thanks to the Kelvin microscope I could directly evidence the Debye-Frankel layer and with it, I could identify cation vacancies at the steps. A real key advantage of alkal ihalides is that they can be doped with divalent metal impurities (Cd, Mg), which produces new phases in the crystals, like the Suzuki phase. Doping of alkali halides leads to nanostructured insulating surfaces, on which the growth of metal NPs can be confined inside specific surface regions at the nanometer scale. With this, metal NPs with a narrow size distribution are created, with interesting potential applications in heterogeneous model catalysis.

Nanosciences of thin molecular films. The second, smaller part of my research is located in the nanosciences of thin molecular films. On insulating alkali halide surfaces I'm interested in the detailed mechanisms of adsorption and desorption of functionalized molecules. Functionalization of molecules with polar substituents and the charge matching principle, i.e. the electrostatic interaction between polar functional groups of molecules and the ionic sublattices of the surface, are of key interest. Furthermore, phenomena of self-assembly and chirality within molecular films are part of my research. In recent years, I focused on pentahelicene molecules ([5]helicene), functionalized with one or two bromine or cyano substituents (MonoBromo, DiBromo, MonoCyano, DiCyano [5]helicene). The detailed adsorption and self-assembly mechanisms could be described in great detail on the Suzuki NaCl surface.

Atomic force microscopy. The local morphological, structural and electrostatic properties of surfaces are studied at the nanometer and atomic scale with help of local scanning probe techniques in ultra-high vacuum and mostly at room temperature. Because of the insulating character of the materials I use frequency modulated nc-AFM (dynamic SFM), which permits obtaining true atomic resolution imaging. Furthermore, the Kelvin microscope (KPFM) supports the characterization of surfaces and supported nano-objects by detecting the electrostatics of the surface, e.g. the surface work function (WF), and charge and polarization related phenomena. Apart from standard nc-AFM and KPFM, I also have a large interest in the manipulation of metal NPs, including lateral manipulation and charge injection experiments.

nc-AFM: Atomic resolution imaging, constant height mode imaging, force spectroscopy, surface structure determination and identification of atoms, ions and adsorbates, high-resolution imaging of metal NPs, manipulation of metal NPs, molecular resolution

KPFM: Quantitative WF measurements of metal supported thin ionic films, imaging charged defects and charge identification on insulating surfaces, quantitative WF measurements at metal NPs, revealing phenomena like contamination, reactivity related phenomena at metal NPs revealed by WF measurements, charge phenomena at metal NPs, characterization and identification of polar tips, dipole imaging at molecules on insulating surfaces

Publications

2019

Oxygen Adsorption on Graphene-Encapsulated Palladium Nanoparticles Imaged by Kelvin Probe Force Microscopy

Henrik Grönbeck, Clemens Barth

Journal of Physical Chemistry C 123:24615-24625 (2019)10.1021/acs.jpcc.9b07377

Revealing Carbon Phenomena at Palladium Nanoparticles by Analyzing the Work Function

Henrik Grönbeck, Clemens Barth

Journal of Physical Chemistry C 123:4360-4370 (2019)10.1021/acs.jpcc.8b12208

2018

Carbon Precursor Structures and Graphene on Palladium Nanoparticles

Clemens Barth

Journal of Physical Chemistry C 122:522-529 (2018)10.1021/acs.jpcc.7b09885

Stability of Ultrathin Ceria Films on Pt(111) Exposed to Air and Treated in Redox Cycles

Gabriele Gasperi, Paola Luches, Clemens Barth

Journal of Physical Chemistry C 122:25954-25963 (2018)10.1021/acs.jpcc.8b07231

2017

Surface Stabilizes Ceria in Unexpected Stoichiometry

Reinhard Olbrich, Gustavo Murgida, Valeria Ferrari, Clemens Barth, Ana Llois, Michael Reichling, M Veronica Ganduglia-Pirovano

Journal of Physical Chemistry C 121:6844-6851 (2017)10.1021/acs.jpcc.7b00956

CO Chemisorption on Ultrathin MgO-Supported Palladium Nanoparticles

Aimeric Ouvrard, Ahmed Ghalgaoui, Carine Michel, Clemens Barth, Jijin Wang, Serge Carrez, Wanquan Zheng, Claude R. Henry, Bernard Bourguignon

Journal of Physical Chemistry C 121:5551-5564 (2017)10.1021/acs.jpcc.6b10595

2016

Advances in the Development of a 10-kA Class REBCO Cable for the EuCARD2 Demonstrator Magnet

A. Badel, A. Ballarino, C. Barth, L. Bottura, M. M. J. Dhalle, J. Fleiter, W. Goldacker, J. Himbele, A. Kario, L. Rossi, A. Rutt, C. Scheuerlein, C. Senatore, P. Tixador, A. Usoskin, Y. Yang

IEEE Transactions on Applied Superconductivity 26:4803908 (2016)10.1109/TASC.2016.2548938

Charging C-60 islands with the AFM tip

Brice Hoff, Claude R. Henry, Clemens Barth

Nanoscale 8:411-419 (2016)10.1039/c5nr04541j

2015

KCl ultra-thin films with polar and non-polar surfaces grown on Si(111)7x7

Igor Beinik, Clemens Barth, Margrit Hanbücken, Laurence Masson

Scientific Reports 5 (2015)10.1038/srep08223

Morphology, Work Function, and Silver Ad-Structures of High-Temperature Grown Ultrathin MgO Films on Ag(001)

F. Mechehoud, C. Barth

Journal of Physical Chemistry C 119:23990 (2015)

2014

Mechanisms of the Adsorption and Self-Assembly of Molecules with Polarized Functional Groups on Insulating Surfaces

B. Hoff, M. Gingras, R. Peresutti, C. R. Henry, A. S. Foster, C. Barth

Journal of Physical Chemistry C 118:14569-14578 (2014)

2013

Defect mediated manipulation of nanoclusters on an insulator

T. Hynninen, Gregory Cabailh, A.S. Foster, C. Barth

Scientific Reports 3:1270 (2013)10.1038/srep01270

Atomic Structures of Silicene Layers Grown on Ag(111) : Scanning Tunneling Microscopy and Noncontact Atomic Force Microscopy Observations

A. Resta, T. Leoni, C. Barth, A. Ranguis, C. Becker, T. Bruhn, P. Vogt, G. Le Lay

Scientific Reports 3:2399 (2013)

Atomic Structures of Silicene Layers Grown on Ag(111): Scanning Tunneling Microscopy and Noncontact Atomic Force Microscopy Observations

Andrea Resta, Thomas Leoni, Clemens Barth, Alain Ranguis, Conrad Becker, Thomas Bruhn, Patrick Vogt, Guy Le Lay

Scientific Reports 3 (2013)

2012

Two-Dimensional Nanostructured Growth of Nanoclusters and Molecules on Insulating Surfaces

C. Barth, M. Gingras, A.S. Foster, A. Gulans, G. Félix, T. Hynninen, R. Peresutti, C.R. Henry

Advanced Materials 24:3228-3232 (2012)

Thin NaCl films on silver (001): island growth and work function

Gregory Cabailh, Claude R Henry, Clemens Barth

New Journal of Physics 14:103037 (2012)10.1088/1367-2630/14/10/103037

Characterization of atomic step structures on CaF2(111) by their electric potential

H.H. Pieper, C. Barth, M. Reichling

Applied Physics Letters 101:051601 (2012)

2011

Recent Trends in Surface Characterization and Chemistry with High-Resolution Scanning Force Methods

C. Barth, A.S. Foster, C.R. Henry, A.L. Shluger

Advanced Materials 23:477-501 (2011)

Polarized Tips or Surfaces: Consequences in Kelvin Probe Force Microscopy

T. Hynninen, A.S. Foster, C. Barth

e-Journal of Surface Science and Nanotechnology 9:6-14 (2011)

Small Molecule-Mediated Activation of the Integrin CD11b/CD18 Reduces Inflammatory Disease

D. Maiguel, M. Faridi, C. Wei, Y. Kuwano, K. Balla, D. Hernandez, C. Barth, G. Lugo, M. Donnelly, A. Nayer, L. Moita, S. Schurer, D. Traver, P. Ruiz, R. Vazquez-Padron, K. Ley, J. Reiser, V. Gupta

Science Signaling 4:ra57-ra57 (2011)10.1126/scisignal.2001811

Characterization of Thin MgO Films on Ag(001) by Low-Energy Electron Diffraction and Scanning Tunneling Microscopy

A. Ouvrard, J. Niebauer, A. Ghalgaoui, C. Barth, C.R. Henry, B. Bourguignon

Journal of Physical Chemistry C 115:8034-8041 (2011)

2010

AFM tip characterization by Kelvin probe force microscopy

C. Barth, T. Hymninen, M. Bieletzki, C.R. Henry, A.S. Foster, F. Esch, U. Heiz

New Journal of Physics 12:093024 (2010)

Topography and work function measurements of thin MgO(001) films on Ag(001) by nc-AFM and KPFM

M. Bielezki, T. Soini, M. Pivetta, C.R. Henry, A.S. Foster, F. Esch, C. Barth, U. Heiz

Physical Chemistry Chemical Physics 12:3203-3209 (2010)

TEM-assisted dynamic scanning force microscope imaging of (001) antigorite: Surfaces and steps on a modulated silicate

E. Palacios-Lidon, O. Grauby, C. Henry, J.-P. Astier, C. Barth, Alain Baronnet

American Mineralogist 95:673 (2010)

Ultrathin magnesia films as support for molecules and metal clusters: Tuning reactivity by thickness and composition

M.E. Vaida, T.M. Bernhardt, C. Barth, F. Esch, U. Heiz, U. Landman

physica status solidi (b) 247:1001-1015 (2010)

2009

Kelvin probe force microscopy on MgO(001) surfaces and supported Pd nanoclusters

C. Barth, C.R. Henry

Journal of Physical Chemistry C 113:247-253 (2009)

Chemical Identification of Ions in Doped NaCl by Scanning Force Microscopy

A.S. Foster, C. Barth, C. Henry

Physical Review Letters 102:256103 (2009)

Expeditive Syntheses of Functionalized Pentahelicenes and NC-AFM on Ag(001)

S. Goretta, C. Tasciotti, Séverine Mathieu, M. Smet, W. Maes, Y.M. Chabre, W. Dehaen, R. Giasson, J.-M. Raimundo, C. Henry, C. Barth, M. Gingras

Organic Letters 11:3846-3849 (2009)