Conrad Becker
Molecular layers, nanoparticles, heterogeneous catalysis, alloys, STM
- Nanostructured surfaces
- Model catalysts
- Molecular films
- Low-temperature scanning tunneling microscopy
- Adsorption on bimetallic surfacesReactivity of bimetallic surfaces
Oxide supported bimetallic nanoparticles
We use a template-controlled approach for the fabrication of well organized arrays of bimetallic nanoparticles on thin alumina films on Ni3Al(111). The morphology and the size of the nanoparticles is characterized by STM. The reactivity as a function of the nanoparticles size and composition can be monitored using molecular beam reactive scattering (MBRS).
Thin films of organic semiconductors
In this field of research we focus our attention to molecules, which are synthesized in the Molecular Engineering Department of the CINaM. Two classes of molecules are currently under investigation: azapentacenes and oligophenylenevinylene. These molecules are deposited by physical vapor deposition on single crystal surfaces (metals and thin oxide films) and are analyzed using STM, STS, and nc-AFM. _/This activity is supported by the Austrian FWF and the French ANR via the project: {{GroPolOMol}} (Growth of polar organic molecules on graphene and sapphire) ANR-14-CE34-0003
Microscopy and Optical Spectroscopy of Organic Layers
By combining microscopic and spectroscopic techniques we will correlate the structural and morphological properties of the molecular layers with their electronic and optical properties and to gain a deeper insight into the structure-property relationship of the organic layers. As a model system we will study the adsorption of (DHTAP) molecules on pristine and modified Cu(110) surfaces. The substrate modification is achieved by pre-adsorption of oxygen or nitrogen, inducing different surface reconstructions that significantly alter the structural, electronic and chemical properties at the Cu(110) surface. In this way, we want to explore the influence of the metal-organic interface on the adsorption and growth of the DHTAP molecules, their structure and orientation on the surface, as well as the ensuing electronic and optical properties of the organic layers.
This activity is supported by the Austrian Agency for International Cooperation in Education and Research (OeAD) Project No. FR 12/2017 and Campus France PHC AMADEUS 2017 projet No. 38069TB (MOSOL).
- Professor of Physics at CINaM, Aix-Marseille University, France
- Habilitation in Physical Chemistry, University of Bonn, Germany
- Scientist at the Institute of Physical and Theoretical Chemistry, University of Bonn, Germany
- Postdoc at CRMC2, Marseille, France
- PhD in Physical Chemistry at University of Bonn, Germany
2024
High-Order Commensurate Zwitterionic Quinonoid Phase Induces a Nanoscale Dipole Lattice on Graphene
Gaelle Nassar, Diego Cortés-Arriagada, Luis Sanhueza-Vega, Périne Landois, Matthieu Paillet, Haitham Hrich, Sylvie Contreras, Olivier Siri, Simon Pascal, Laurence Masson, Conrad Becker, Alain Ranguis, Romain Parret, Gabriel Canard, Thomas Leoni
Journal of Physical Chemistry C 128:9712-9721 (2024)10.1021/acs.jpcc.4c01695
2023
Electrical monitoring of organic crystal phase transition using MoS2 field effect transistor
Ilan Boulet, Simon Pascal, F. Bedu, Igor Ozerov, Alain Ranguis, Thomas Leoni, Conrad Becker, Laurence Masson, Aleksandar Matkovic, Christian Teichert, Olivier Siri, Claudio Attaccalite, Jean-Roch Huntzinger, Matthieu Paillet, Ahmed-Azmi Zahab, Romain Parret
Nanoscale Advances 5:1681-1690 (2023)10.1039/d2na00817c
2022
A one-dimensional high-order commensurate phase of tilted molecules
Anthony Thomas, Thomas Leoni, Olivier Siri, Conrad Becker, Martin Unzog, Christian Kern, Peter Puschnig, Peter Zeppenfeld
Physical Chemistry Chemical Physics 24:9118-9122 (2022)10.1039/d2cp00437b
2021
On-surface chemistry using local high electric fields
Thomas Leoni, Tony Lelaidier, Anthony Thomas, Alain Ranguis, Olivier Siri, Claudio Attaccalite, Conrad Becker
Nanoscale Advances (2021)10.1039/d1na00383f
On-surface chemistry using local high electric fields
Thomas Leoni, Tony Lelaidier, Anthony Thomas, Alain Ranguis, Olivier Siri, Claudio Attaccalite, Conrad Becker
Nanoscale Advances 3:5565-5569 (2021)10.1039/d1na00383f
Stereoisomeric selection upon adsorption: A structural and optical study of curcuminoid derivatives on ultrathin films of KCl on Au(111) and on KCl(001) bulk
Thomas Leoni, Laurent Nony, Elena Zaborova, Sylvain Clair, Frédéric Fagès, Franck Para, Alain Ranguis, Conrad Becker, Christian Loppacher
Physical Review B 104 (2021)10.1103/PhysRevB.104.205415
2019
Light‐Assisted Charge Propagation in Networks of Organic Semiconductor Crystallites on Hexagonal Boron Nitride
Aleksandar Matković, Jakob Genser, Markus Kratzer, Daniel Lüftner, Zhongrui Chen, Olivier Siri, Peter Puschnig, Conrad Becker, Christian Teichert
Advanced Functional Materials 1903816 (2019)10.1002/adfm.201903816
2018
Noncontact AFM and differential reflectance spectroscopy joint analyses of bis-pyrenyl thin films on bulk insulators: Relationship between structural and optical properties
Franck Bocquet, Laurent Nony, Franck Para, Philipda Luangprasert, Jean-Valère Naubron, Christian Loppacher, Thomas Leoni, Anthony Thomas, Alain Ranguis, Anthony d'Aléo, Frédéric Fages, Conrad Becker
Physical Review B: Condensed Matter and Materials Physics (1998-2015) 97 (2018)10.1103/physrevb.97.235434
Growth morphologies of dihydro-tetraaza-acenes on c-plane sapphire
Aleksandar Matković, Aydan Çiçek, Markus Kratzer, Benjamin Kaufmann, Anthony Thomas, Zhongrui Chen, Olivier Siri, Conrad Becker, Christian Teichert
Surface Science : A Journal Devoted to the Physics and Chemistry of Interfaces 678:128-135 (2018)10.1016/j.susc.2018.03.009
Growth of Dihydrotetraazapentacene Layers on Cu(110)
Anthony Thomas, Walter Malone, Thomas Leoni, Alain Ranguis, Zhongrui Chen, Olivier Siri, Abdelkader Kara, Peter Zeppenfeld, Conrad Becker
Journal of Physical Chemistry C 122:10828-10834 (2018)10.1021/acs.jpcc.8b01336
2017
Adsorption and Growth of Bis-pyrene Molecular Layers on Au(111) Studied by STM
Tony Lelaidier, Thomas Leoni, Alain Ranguis, Anthony D’aléo, Frédéric Fages, Conrad Becker
Journal of Physical Chemistry C 121:7214-7220 (2017)10.1021/acs.jpcc.6b12354
Effect of Thiol-Ligands on the Optical Response of Supported Silver Clusters
Tobias Lünskens, Alexander von Weber, Matthias Jakob, Tony Lelaidier, Aras Kartouzian, Ueli Heiz
Journal of Physical Chemistry C 121:9331-9336 (2017)10.1021/acs.jpcc.7b00827
2016
Optical and morphological properties of thin films of bis-pyrenyl pi-conjugated molecules
Tony Lelaidier, Tobias Luenskens, Alexander Weber, Thomas Leoni, Alain Ranguis, Anthony d'Aléo, Fréderic Fages, Aras Kartouzian, Conrad Becker, Ulrich Heiz
Physical Chemistry Chemical Physics 18:5299-5305 (2016)10.1039/c5cp06011g
2015
Distribution of Pd clusters on ultrathin, epitaxial TiO x films on Pt 3 Ti(111)
Christian Breinlich, Maria Buchholz, Marco Moors, Tobias Pertram, Conrad Becker, Klaus Wandelt
2014
Scanning Tunneling Microscopy Investigation of Ultrathin Titanium Oxide Films Grown on Pt 3 Ti(111)
Christian Breinlich, Maria Buchholz, Marco Moors, Séverine Le Moal, Conrad Becker, Klaus Wandelt
2013
Growth of Si ultrathin films on silver surfaces: Evidence of an Ag(110) reconstruction induced by Si
Romain Bernard, Thomas Leoni, Axel Wilson, Tony Lelaidier, Houda Sahaf, Eric Moyen, Loïc Assaud, Lionel Santinacci, Frédéric Leroy, Fabien Cheynis, Alain Ranguis, Haik Jamgotchian, Conrad Becker, Yves Borensztein, Margrit Hanbücken, Geoffroy Prévot, Laurence Masson
Physical Review B: Condensed Matter and Materials Physics (1998-2015) 88 (2013)10.1103/PhysRevB.88.121411
Structural and compositional characterization of ultrathin titanium oxide films grown on Pt 3 Ti(111)
Séverine Le Moal, Marco Moors, Jan Markus Essen, Christian Breinlich, Conrad Becker, Klaus Wandelt
Atomic Structures of Silicene Layers Grown on Ag(111): Scanning Tunneling Microscopy and Noncontact Atomic Force Microscopy Observations
Andrea Resta, Thomas Leoni, Clemens Barth, Alain Ranguis, Conrad Becker, Thomas Bruhn, Patrick Vogt, Guy Le Lay
Scientific Reports 3 (2013)10.1038/srep02399
Atomic Structures of Silicene Layers Grown on Ag(111): Scanning Tunneling Microscopy and Noncontact Atomic Force Microscopy Observations
Andrea Resta, Thomas Leoni, Clemens Barth, Alain Ranguis, Conrad Becker, Thomas Bruhn, Patrick Vogt, Guy Le Lay
2011
Mechanistic and spectroscopic identification of initial reaction intermediates for prenal decomposition on a platinum model catalyst
J. Haubrich, D. Loffreda, F. Delbecq, P. Sautet, Y. Jugnet, A. Krupski, Conrad Becker, K. Wandelt
Physical Chemistry Chemical Physics 13:6000-6009 (2011)10.1039/c0cp02428g
2010
Characterization of bimetallic Au–Pt(111) surfaces
T. Kobiela, M. Moors, W. Linhart, I. Cebula, A. Krupski, Conrad Becker, K. Wandelt
CO adsorption on clean and oxidized Pt3Ti(111)
Séverine Le Moal, Marco Moors, Jan Markus Essen, Conrad Becker, Klaus Wandelt
Surface Science : A Journal Devoted to the Physics and Chemistry of Interfaces 604:1637-1644 (2010)10.1016/j.susc.2010.06.007
Adsorption and reaction of Rh(CO)2(acac) on Al 2 O 3 /Ni3Al(111)
Y. Lei, A. Uhl, Conrad Becker, K. Wandelt, C. Gates, R. Meyer, M. Trenary
Formation of Ruthenium−Tin Nanoparticles on Al 2 O 3 /Ni 3 Al(111) from an Organometallic Precursor
Alexander Uhl, Yu Lei, Homa Khosravian, Conrad Becker, Klaus Wandelt, Richard Adams, Michael Trenary, Randall Meyer
2009
The Adsorption of Ethene on Pd(111) and Ordered Sn/Pd(111) Surface Alloys
G. Hamm, T. Schmidt, J. Breitbach, D. Franke, Conrad Becker, Klaus Wandelt
Adsorption and Vibrations of α,β-Unsaturated Aldehydes on Pt(111) and Pt−Sn Alloy (111) Surfaces. 3. Adsorption Energy vs Adsorption Strength
J. Haubrich, D. Loffreda, F. Delbecq, P. Sautet, Y. Jugnet, Conrad Becker, K. Wandelt
Journal of Physical Chemistry C 114:1073-1084 (2009)10.1021/jp908353p
Adsorption and interaction energy of π ethene on Pt(111) and Pt alloys: A detailed analysis of vibrational, energetic and electronic properties
J. Haubrich, Conrad Becker, K. Wandelt
Surface Science : A Journal Devoted to the Physics and Chemistry of Interfaces 603:1476-1485 (2009)
Adsorption of α,β-Unsaturated Aldehydes on Pt(111) and Pt−Sn Alloys: II. Crotonaldehyde
J. Haubrich, D. Loffreda, F. Delbecq, P. Sautet, A. Krupski, Conrad Becker, K. Wandelt
Journal of Physical Chemistry C 113:13947-13967 (2009)10.1021/jp903473m
2008
Pd(110) surface oxide structures investigated by STM and DFT
M. Kralj, T. Pertram, N. Seriani, F. Mittendorfer, A. Krupski, Conrad Becker, K. Wandelt
Surface Science : A Journal Devoted to the Physics and Chemistry of Interfaces 602:3706-3713 (2008)
Scanning tunneling microscopy and spectroscopy investigations of copper phthalocyanine adsorbed on Al2O3/Ni3Al(111)
M. Moors, A. Krupski, S. Degen, M. Kralj, Conrad Becker, K. Wandelt