Electrochimie
De nouveaux donneurs et accepteurs d’électrons forts sont caractérisés en terme de propriétés redox. Les systèmes redox réversibles présentent des propriétés électrochromiques et changent de couleur selon le potentiel appliqué. De tels systèmes sont des composants incontournables des matériaux électroconducteurs d’affichages électrochromes.
Calculs de mécanique quantique
La chimie quantique est un outil indispensable pour prédire les propriétés de composés jusqu’alors inconnus avant même de développer leur synthèse.
Quelques références
Lokshin, V., Khodorkovsky, V. (2018). Stereochemistry in control of photochemical reactivity: 2,6-Diaryl-4 H -spiro[cyclohexane-1,2′-indene]-1′,3′,4-triones. Tetrahedron, 74(3), 418-424.
Bekere, L., Lokshin, V., Sigalov, M., Gvishi, R., Zhao, P., Hagan, D. J., Khodorkovsky, V. (2016). Chromenes involving a two-photon absorbing moiety: photochromism via intramolecular resonance energy transfer. New J. Chem., 40 (2), 1143-1148.
Lokshin, V., Bekere, L., Khodorkovsky, V. (2017). Visual light photoswitches derived from bindone: Toward stabilization of colored photo-isomers. Dyes and Pigments, 145, 570-575.
Niebel, C., Lokshin, V., & Khodorkovsky, V. (2010). Octacyanotetramethylene-substituted dicyclopentanaphthalene: a new anionic electron acceptor with multi-stage reversible redox behavior. Tetrahedron Letters, 51(6), 949-951.
Bar, G., Larina, N., Grinis, L., Lokshin, V., Gvishi, R., Kiryuschev, I., Khodorkovsky, V. (2012). RGB organic electrochromic cells. Solar Energy Materials and Solar Cells, 99, 123-128.
2024
Tuning the Electronic Properties of Bridged Dithienyl‐, Difuryl‐, Dipyrrolyl‐Vinylene as Precursors of Small‐Bandgap Conjugated Polymer.
Jordan Garo, Tommaso Nicolini, Jean-Marc Sotiropoulos, Jean‐manuel Raimundo
Chemistry - A European Journal 30:e202402461 (2024)10.1002/chem.202402461
Self-assembled monolayers of push-pull chromophores as active layer and their applications
Junlong Wang, Virginie Gadenne, Lionel Patrone, Jean-Manuel Raimundo
Molecules 29:559 (2024)10.3390/molecules29030559
2022
Naked-Eye Chromogenic Test Strip for Cyanide Sensing Based on Novel Phenothiazine Push–Pull Derivatives
Pedro Martín Várguez, Jean-Manuel Raimundo
Biosensors 12:407 (2022)10.3390/bios12060407
Affinity driven ion exchange EG-OFET sensor for high selectivity and low limit of detection of Cesium in seawater
Tin Phan Nguy, Volkan Kilinc, Ryoma Hayakawa, Catherine Henry-De-Villeneuve, Jean-Manuel Raimundo, Yutaka Wakayama, Anne Charrier
Sensors and Actuators B: Chemical 351:130956 (2022)10.1016/j.snb.2021.130956
Affinity driven ion exchange EG-OFET sensor for high selectivity and low limit of detection of cesium in seawater
Tin Phan Nguy, Volkan Kilinc, Ryoma Hayakawa, Catherine Henry-De-Villeneuve, Jean-Manuel Raimundo, Yutaka Wakayama, Anne Charrier
Sensors and Actuators B: Chemical 351:130956 (2022)10.1016/j.snb.2021.130956
Conjugated donor–acceptor substituted systems involving the 1,3-indandione-derived electron accepting moieties
Mark Sigalov, Royi Mazor, Arkady Ellern, Nina Larina, Vladimir Lokshin, Vladimir Khodorkovsky
RSC Advances 12:27766-27774 (2022)10.1039/d2ra05335g
2021
Dipole moments of conjugated donor–acceptor substituted systems: calculations vs. experiments
Vladimir Lokshin, Mark Sigalov, Nina Larina, Vladimir Khodorkovsky
RSC Advances 11:934-945 (2021)10.1039/d0ra10182f
Light-Induced Reactions within Poly(4-vinyl pyridine)/Pyridine Gels: The 1,6-Polyazaacetylene Oligomers Formation
Evgenia Vaganova, Dror Eliaz, Ulyana Shimanovich, Gregory Leitus, Emad Aqad, Vladimir Lokshin, Vladimir Khodorkovsky
Molecules 26:6925 (2021)10.3390/molecules26226925
2020
Control of the optical properties upon a reversible [2+2] cycloaddition of 3-(4-N,N-dibutylamino)-styryl)-3’-(dicyanovinyl)-bithiophene
Hecham Aboubakr, Jean-Marc Sotiropoulos, Hugues Brisset, Jean-Manuel Raimundo
Tetrahedron 76:131384 (2020)10.1016/j.tet.2020.131384
Phosphonium-ammonium-based di-cationic ionic liquids as antibacterial over the ESKAPE group
Frédéric Brunel, Christelle Lautard, Frédéric Garzino, Jean-Manuel Raimundo, Jean-Michel Bolla, Michel Camplo
Bioorganic and Medicinal Chemistry Letters 30:127389 (2020)10.1016/j.bmcl.2020.127389
Femtomolar detection of Cu2+ ions in solution using super-Nernstian FET-sensor with a lipid monolayer as top-gate dielectric
A. Kenaan, F. Brunel, J.-M. Raimundo, Anne Charrier
Sensors and Actuators B: Chemical 316:128147 (2020)10.1016/j.snb.2020.128147
Spiro 1,3-indandiones: intramolecular photochemical reactions of carbonyl groups with carbon-carbon double bonds
Vladimir Lokshin, Hervé Clavier, Vladimir Khodorkovsky
New Journal of Chemistry 44:14373-14378 (2020)10.1039/D0NJ02923H
Recent Electrochemical/Electrical Microfabricated Sensor Devices for Ionic and Polyionic Analytes
Pedro Martín Várguez, Frédéric Brunel, Jean-Manuel Raimundo
ACS Omega 5:4733-4742 (2020)10.1021/acsomega.9b04331
Electrolyte-gated-organic field effect transistors functionalized by lipid monolayers with tunable pH sensitivity for sensor applications
Tin Phan Nguy, Ryoma Hayakawa, Volkan Kilinc, Matthieu Petit, Yemineni S L V Narayana, Masayoshi Higuchi, Jean-Manuel Raimundo, Anne Charrier, Yutaka Wakayama
Applied Physics Express 13:011005 (2020)10.7567/1882-0786/ab5322
Hindered rotational barriers in conjugated donor–acceptor substituted systems: calculations vs. experiments
Mark Sigalov, Vladimir Lokshin, Nina Larina, Vladimir Khodorkovsky
Physical Chemistry Chemical Physics 22:1214-1221 (2020)10.1039/c9cp06234c
2019
1,2,3,4-Tetrahydro-1,4,5,8-tetraazaanthracene revisited: properties and structural evidence of aromaticity loss
Arnault Heynderickx, Sébastien Nénon, Olivier Siri, Vladimir Lokshin, Vladimir Khodorkovsky
Beilstein Journal of Organic Chemistry 15:2059-2068 (2019)10.3762/bjoc.15.203
Novel and Innovative Interface as Potential Active Layer in Chem-FET Sensor Devices for the Specific Sensing of Cs+
Volkan Kilinc, Catherine Henry-De-Villeneuve, Tin Phan Nguy, Yutaka Wakayama, Anne M Charrier, Jean-Manuel Raimundo
ACS Applied Materials & Interfaces 11:47635-47641 (2019)10.1021/acsami.9b18188
Novel and innovative interface as potential active layer in Chem-FET sensor devices for the specific sensing of Cs
Volkan Kilinc, Catherine Henry-De-Villeneuve, Tin Phan Nguy, Yutaka Wakayama, Anne Charrier, Jean-Manuel Raimundo
ACS Applied Materials & Interfaces 11:47635-47641 (2019)10.1021/acsami.9b18188
Bacterial anti-adhesion activity based on the electrochemical properties of polymethacrylates bearing ferrocenyl pendant groups
Ronald Nguema Edzang, The Hy Duong, Jean-François Briand, Marlene Lejars, Jean-Manuel Raimundo, Christine Bressy, Hugues Brisset
Biofouling 34:1055-1063 (2019)10.1080/08927014.2018.1539165
Stable operation of water-gated organic field-effect transistor depending on channel flatness, electrode metals and surface treatment
Tin Phan Nguy, Ryoma Hayakawa, Volkan Kilinc, Matthieu Petit, Jean-Manuel Raimundo, Anne Charrier, Yutaka Wakayama
Japanese Journal of Applied Physics 58:SDDH02 (2019)10.7567/1347-4065/ab09d2
What Can Be Learned from the Polymerization of a Pyridine‐Based Two‐Component System
Evgenia Vaganova, Faina Dubnikov, Ellina Kesselman, Vladimir Lokshin, Vladimir Khodorkovsky
Macromolecular Symposia 385:1800157 (2019)10.1002/masy.201800157
2018
A red to blue series of push-pull dyes for NiO based p-DSSCs.
Romain Brisse, Praveen Chandrasekar, Valentin Maffeis, Tiphaine Bourgeteau, Denis - Tondelier, Thomas Berthelot, Bernard Geffroy, Thomas Gustavsson, Jean-Manuel Raimundo, Bruno Jousselme
Sustainable Energy & Fuels 2:648-654 (2018)10.1039/C7SE00474E
Antibacterial activities of mono-, di- and tri-substituted triphenylamine-based phosphonium ionic liquids
Frédéric Brunel, Christelle Lautard, Carole Di Giorgio, Frédéric Garzino, Jean-Manuel Raimundo, Jean-Michel Bolla, Michel Camplo
Bioorganic and Medicinal Chemistry Letters 28:926-929 (2018)10.1016/j.bmcl.2018.01.057
Ultra-thin supported lipid monolayer with unprecedented mechanical and dielectric properties
Ahmad Kenaan, Racha El Zein, Volkan Kilinc, Sébastien Lamant, Jean-Manuel Raimundo, Anne Charrier
Advanced Functional Materials 1801024 (2018)10.1002/adfm.201801024
Stereochemistry in control of photochemical reactivity: 2,6-Diaryl-4 H -spiro[cyclohexane-1,2′-indene]-1′,3′,4-triones
Vladimir Lokshin, Vladimir Khodorkovsky
Tetrahedron 74:418-424 (2018)10.1016/j.tet.2017.12.014
Stereochemistry in control of photochemical reactivity: 2,6-Diaryl-4H-spiro[cyclohexane-1,2′-indene]-1′,3′,4-triones
Vladimir Lokshin, Vladimir Khodorkovsky
Tetrahedron 74:418-424 (2018)10.1016/j.tet.2017.12.014
Thiol-functionalization of Mn5Ge3 thin films
Marta K Schütz, Matthieu Petit, Lisa Michez, Alain Ranguis, Guillaume Monier, Christine Robert-Goumet, Jean-Manuel Raimundo
Applied Surface Science 451:191-197 (2018)10.1016/j.apsusc.2018.04.231
2017
Visual light photoswitches derived from bindone: Toward stabilization of colored photo-isomers
Vladimir Lokshin, Laura Bekere, Vladimir Khodorkovsky
Dyes and Pigments 145:570-575 (2017)10.1016/j.dyepig.2017.06.052
Synthesis and characterization of thiophene-based push-pull chromophores for tuning the electrical and optical properties of surfaces with controlled SAM formation
Volodymyr Malytskyi, Virginie Gadenne, Younal Ksari, Lionel Patrone, Jean-Manuel Raimundo
Tetrahedron 73:5738-5744 (2017)10.1016/j.tet.2017.08.004
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Nanohybrids for multiphoton excitation (NEM). ANR Blanc. ANR, 2009- 2011.
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Color photo technology for electronic ID documents (COSEC-ID), (Euripides certified, Ministry of Industry) 2010 – 2014.
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Preparation of one-photon absorbing photochromes. KILOLAMBDA TECHNOLOGIES, LTD, 2017.
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Spectrophotomètre UV-Vis JASCO
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Système avancé de mesure d’absorption et de fluorescence
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Potentiostat
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A mechanism and apparatus by which visual information and/or color images may be securely and inexpensively personalized onto physical media by selectively bleaching color components
J.-L. Lesur, J. Leibenguth, V. Khodorkovsky, N. Larina, V. Lokshin, M. Maciejczyk. Patent application. CNRS Ref. No 06214-01.