Department IMMF

Molecular Engineering and Functional Materials

Leader: Olivier Margeat

Introduction

The research activities of the "Molecular Engineering and Functional Materials" department (IMMF) stand at the interface of chemistry-physics-biology and focus on the synthesis, the physico-chemical characterization and the property studies of organic, inorganic and/or hybrid molecular structures.

These activities are divided around three research themes:

 


Nanomedicine
Biomaterials

 

  • Vectorization

 

  • Bioimaging / Diagnostic

 

  • Therapy

 


Singular conjugated
structures

 

  • Engineering of chromophores and fluorophores

 

  • Molecular switches

 

  • Supramolecular chemistry

 


Surfaces, thin films
& devices

 

  • Assemblies on surface

 

  • Functional coatings

 

  • Optoelectronic devices

 

Publications

2024

Correlation between materials and band‐selective detection in organic photodetectors based on bulk heterojunction

Quentin Eynaud, Anass Khodr, Mohamed El Amine Kramdi, Gilles Quéléver, Olivier Margeat, Jörg Ackermann, Christine Videlot-Ackermann

Journal of Applied Polymer Science (2024)10.1002/app.55481

Toward Air Stability of Efficient Filter‐Free Band‐Selective Organic Photodetectors Based on Bulk Heterojunction: Avoiding Environmental Degradation with Atomic Layer Deposition Encapsulation

Quentin Eynaud, Mohamed El Amine Kramdi, Vyshnav Kannampalli, Tomoyuki Koganezawa, Noriyuki Yoshimoto, Lionel Santinacci, Jörg Ackermann, Christine Videlot-Ackermann

Advanced Energy and Sustainability Research 2300262 (2024)10.1002/aesr.202300262

Two-step access to bis- meso -perfluoroalkyl-corroles towards meso -perfluoroacyl-ABC-corroles

Paul-Gabriel Julliard, Simon Pascal, Olivier Siri, Michel Giorgi, Diego Cortés-Arriagada, Luis Sanhueza, Gabriel Canard

Organic & Biomolecular Chemistry (2024)10.1039/D4OB00191E

Insights into the relationship between molecular and order-dependent photostability of ITIC derivatives for the production of photochemically stable blends

Y. Quiroz Avalos, Quentin Eynaud, Pavlo Perkhun, Agnès Rivaton, Wolfgang Köntges, Rasmus R Schröder, Tomoyuki Koganezawa, Noriyuki Yoshimoto, A. Kumar Bharwal, David Duché, Carmen M M Ruiz, Olivier Margeat, Cyril Aumaitre, Renaud Demadrille, Christine Videlot-Ackermann, Jörg Ackermann

Journal of Materials Chemistry C (2024)10.1039/D3TC04614A

2023

Design of infrared optical absorber using silver nanorings array made by a top-down process

Ibtissem Bouanane, F. Bedu, Igor Ozerov, Beniamino Sciacca, Lionel Santinacci, David Duché, Gérard Berginc, Ludovic Escoubas, Olivier Margeat, Judikaël Le Rouzo

Scientific Reports 13:7770 (2023)10.1038/s41598-023-34579-w

Electrical monitoring of organic crystal phase transition using MoS2 field effect transistor

Ilan Boulet, Simon Pascal, F. Bedu, Igor Ozerov, Alain Ranguis, Thomas Leoni, Conrad Becker, Laurence Masson, Aleksandar Matkovic, Christian Teichert, Olivier Siri, Claudio Attaccalite, Jean-Roch Huntzinger, Matthieu Paillet, Ahmed-Azmi Zahab, Romain Parret

Nanoscale Advances 5:1681-1690 (2023)10.1039/d2na00817c

Nanoparticle Imprint Lithography: From Nanoscale Metrology to Printable Metallic Grids

Anna Capitaine, Mehrnaz Bochet-Modaresialam, Peeranuch Poungsripong, Clémence Badie, Vasile Heresanu, Olivier Margeat, Lionel Santinacci, David Grosso, Erik Garnett, Beniamino Sciacca

ACS Nano (2023)10.1021/acsnano.3c01156

Progress and Harmonization of Gene Editing to Treat Human Diseases (Proceeding of COST Action CA21113 GenE-HumDi)

Alessia Cavazza, Ayal Hendel, Rasmus O Bak, Paula Rio, Marc Güell, Duško Lainšček, Virginia Arechavala-Gomeza, Ling Peng, Fatma Zehra Hapil, Joshua Harvey, Francisco G Ortega, Coral Gonzalez-Martinez, Carsten W Lederer, Kasper Mikkelsen, Giedrius Gasiunas, Nechama Kalter, Manuel a F V Gonçalves, Julie Petersen, Alejandro Garanto, Lluis Montoliu, Marcello Maresca, Stefan E Seemann, Jan Gorodkin, Loubna Mazini, Rosario Sanchez, Juan R Rodriguez-Madoz, Noelia Maldonado-Pérez, Torella Laura, Michael Schmueck-Henneresse, Cristina Maccalli, Julian Grünewald, Gloria Carmona, Neli Kachamakova-Trojanowska, Annarita Miccio, Francisco Martin, Giandomenico Turchiano, Toni Cathomen, Yonglun Luo, Shengdar Q Tsai, Karim Benabdellah

Molecular Therapy - Nucleic Acids (2023)10.1016/j.omtn.2023.102066

Cargo-selective and adaptive delivery of nucleic acid therapeutics by bola-amphiphilic dendrimers

Jiaxuan Chen, Dandan Zhu, Baoping Lian, Kangjie Shi, Peng Chen, Ying Li, Wenyi Lin, Ling Ding, Qiulin Long, Yang Wang, Erik Laurini, Wenjun Lan, Yun Li, Aura Tintaru, Caoyun Ju, Can Zhang, Sabrina Pricl, Juan Iovanna, Xiaoxuan Liu, Ling Peng

Proceedings of the National Academy of Sciences of the United States of America 120:e2220787120 (2023)10.1073/pnas.2220787120

Modular Self‐Assembling Dendrimer Nanosystems for Magnetic Resonance And Multimodality Imaging of Tumors

Ling Ding, Zhenbin Lyu, Teodora‐adriana Perles-Barbacaru, Adela Ya‐ting Huang, Baoping Lian, Yifan Jiang, Tom Roussel, Christina Galanakou, Suzanne Giorgio, Chai‐lin Kao, Xiaoxuan Liu, Juan Iovanna, Monique Bernard, Angèle Viola, Ling Peng

Advanced Materials (2023)10.1002/adma.202308262

Enzyme-immobilized hierarchically porous covalent organic framework biocomposite for catalytic degradation of broad-range emerging pollutants in water

Nada Elmerhi, Khadega Al-Maqdi, Khawlah Athamneh, Abdul Khayum Mohammed, Tina Skorjanc, Felipe Gándara, Jesus Raya, Simon Pascal, Olivier Siri, Ali Trabolsi, Iltaf Shah, Dinesh Shetty, Syed Salman Ashraf

Journal of Hazardous Materials 459:132261 (2023)10.1016/j.jhazmat.2023.132261

Towards efficient NFA-based selective near-infrared organic photodetectors: impact of thermal annealing of polymer blends

Q. Eynaud, Y. Avalos Quiroz, T. Koganezawa, R. Sato, N. Yoshimoto, O. Margeat, C. Ruiz, J. Ackermann, Christine Videlot-Ackermann

Journal of Materials Chemistry C 11:9657-9669 (2023)10.1039/D3TC01180A

Azacalixphyrin nanostructures

Daniel Ferry, Sabrina Pricl, Domenico Marson, Zhongrui Chen, Gabriel Canard, Simon Pascal, Aura Tintaru, Olivier Siri

Journal of Porphyrins and Phthalocyanines (2023)10.1142/S1088424623500785

Amphiphilic dendrimers against antibiotic resistance: light at the end of the tunnel?

Christina Galanakou, Dinesh Dhumal, Ling Peng

Biomaterials Science (2023)10.1039/D2BM01878K

Dendrimer nanosystems for adaptive tumor-assisted drug delivery via extracellular vesicle hijacking

Yifan Jiang, Zhenbin Lyu, Brigino Ralahy, Juan Liu, Tom Roussel, Ling Ding, Jingjie Tang, Artemis Kosta, Suzanne Giorgio, Richard Tomasini, Xing-Jie Liang, Nelson Dusetti, Juan Iovanna, Ling Peng

Proceedings of the National Academy of Sciences of the United States of America 120 (2023)10.1073/pnas.2215308120

Core–Shell Multiwalled Carbon Nanotube/Cobalt Corrole Hybrids for the Oxygen Reduction Reaction

Paul-Gabriel Julliard, Manel Hanana, Laurent Alvarez, Renaud Cornut, Bruno Jousselme, Gabriel Canard, Stéphane Campidelli

Energy & Fuels 37:684-692 (2023)10.1021/acs.energyfuels.2c03434

The Diversity of Cucurbituril Molecular Switches and Shuttles

Anthony Kermagoret, David Bardelang

Chemistry - A European Journal 29 (2023)10.1002/chem.202302114

Star-shape non-fullerene acceptor featuring an aza-triangulene core for organic solar cells

Yann Kervella, José Maria Andrés Castán, Yatzil Alejandra Avalos-Quiroz, Anass Khodr, Quentin Eynaud, Tomoyuki Koganezawa, Noriyuki Yoshimoto, Olivier Margeat, Agnès Rivaton, Antonio Riquelme, Valid Mwatati Mwalukuku, Jacques Pécaut, Benjamin Grévin, Christine Videlot-Ackermann, Jörg Ackermann, Renaud Demadrille, Cyril Aumaître

Journal of Materials Chemistry C 11:8161-8169 (2023)10.1039/d2tc05424h

A pH-and Metal-Actuated Molecular Shuttle in Water

Amine Kriat, Simon Pascal, Brice Kauffmann, Yann Ferrand, David Bergé-Lefranc, Didier Gigmes, Olivier Siri, Anthony Kermagoret, David Bardelang

Chemistry - A European Journal e202300633 (2023)10.1002/chem.202300633

Controlled oligomeric guest stacking by cucurbiturils in water

Fengbo Liu, Amine Kriat, Roselyne Rosas, David Berge-Lefranc, Didier Gigmes, Simon Pascal, Olivier Siri, Simin Liu, Anthony Kermagoret, David Bardelang

Organic & Biomolecular Chemistry (2023)10.1039/D3OB01723K

Proton-coupled electron transfer in a pivaloyl-substituted dihydro-tetraazapentacene

Jean-François Longevial, Iryna Knysh, Shaymaa Al Shehimy, Lhoussain Khrouz, Arumugam Pandurangan, Simon Pascal, Gabriel Canard, Christophe Bucher, Denis Jacquemin, Olivier Siri

Electrochimica Acta 449:142224 (2023)10.1016/j.electacta.2023.142224

Magnetic functionalization of ZnO nanoparticles surfaces via optically generated methyl radicals

D. Marin, G. Gerbaud, O. Margeat, F. Ziarelli, F. Ferrer, O. Ouari, A. Campos, S. Bertaina, Adrien Savoyant

Journal of Chemical Physics 158:184704 (2023)10.1063/5.0152015

Insights into Extended Coupled Polymethines through the Investigation of Dual UV-to-NIR Acidochromic Switches Based on Heptamethine-Oxonol Dyes

Benjamin Mourot, Valérie Mazan, Mourad Elhabiri, Rudraditya Sarkar, Denis Jacquemin, Olivier Siri, Simon Pascal

Chemical Science (2023)10.1039/D3SC06126D

A Strategy to Design Substituted Tetraamino-Phenazine Dyes and Access to an NIR-Absorbing Benzoquinonediimine-Fused Quinoxaline

Tatiana Munteanu, Valérie Mazan, Mourad Elhabiri, Camil Benbouziyane, Gabriel Canard, Denis Jacquemin, Olivier Siri, Simon Pascal

Organic Letters (2023)10.1021/acs.orglett.3c01251

Synthesis and antimicrobial testing of 5‐fluorouracil derivatives

Mrunal Patil, Krykun Serhii, Frédéric Garzino, Quentin Gobert, Suzanne Giorgio, Jean‐manuel Raimundo, Jean‐michel Bolla, Michel Camplo

Archiv der Pharmazie / Chemistry in Life Sciences 356 (2023)10.1002/ardp.202300103

Deciphering electronic and structural effects in Copper Corrole/Graphene Hybrids

Kerry Wrighton-Araneda, Diego Cortés-Arriagada, Paulina Dreyse, Simon Pascal, Gabriel Canard, Luis Sanhueza

Chemistry - A European Journal (2023)10.1002/chem.202203175

Internal Dynamics and Modular Peripheral Binding in Stimuli‐Responsive 3 : 2 Host:Guest Complexes

Hang Yin, Roselyne Rosas, Stéphane Viel, Michel Giorgi, Valerie Monnier, Laurence Charles, Didier Siri, Didier Gigmes, Youssef Nassar, Floris Chevallier, Christophe Bucher, Ruibing Wang, Anthony Kermagoret, David Bardelang

Angewandte Chemie International Edition (2023)10.1002/anie.202315985

Breaking Azacalix[4]arenes into Induline Derivatives

Chen Zhongrui, Gabriel Canard, Grauby Olivier, Benjamin Mourot, Olivier Siri

Molecules 28 (2023)10.3390/molecules28248113

Financement

Équipe Ackermann 1 Sources et sondes ponctuelles 2 Physique et nano-micro Ingénierie pour le Vivant 1 Équipe Peng Équipe Peng 1

  • ANR contracts

  • 1 Doc2AMU fellowship

  • 1 collaboration contract with Dracula Technologie company

  • 1 AMidex project

  • 1 "Ligue contre le Cancer" labeled team

  • 2 Horizon 2020 contracts