Department IMMF

Molecular Engineering and Functional Materials

Leader: Olivier Margeat

Introduction

The research activities of the "Molecular Engineering and Functional Materials" department (IMMF) stand at the interface of chemistry-physics-biology and focus on the synthesis, the physico-chemical characterization and the property studies of organic, inorganic and/or hybrid molecular structures.

These activities are divided around three research themes:

 


Nanomedicine
Biomaterials

 

  • Vectorization

 

  • Bioimaging / Diagnostic

 

  • Therapy

 


Singular conjugated
structures

 

  • Engineering of chromophores and fluorophores

 

  • Molecular switches

 

  • Supramolecular chemistry

 


Surfaces, thin films
& devices

 

  • Assemblies on surface

 

  • Functional coatings

 

  • Optoelectronic devices

 

Publications

2023

Design of infrared optical absorber using silver nanorings array made by a top-down process

Ibtissem Bouanane, F. Bedu, Igor Ozerov, Beniamino Sciacca, Lionel Santinacci, David Duché, Gérard Berginc, Ludovic Escoubas, Olivier Margeat, Judikaël Le Rouzo

Scientific Reports 13:7770 (2023)10.1038/s41598-023-34579-w

Electrical monitoring of organic crystal phase transition using MoS2 field effect transistor

Ilan Boulet, Simon Pascal, F. Bedu, Igor Ozerov, Alain Ranguis, Thomas Leoni, Conrad Becker, Laurence Masson, Aleksandar Matkovic, Christian Teichert, Olivier Siri, Claudio Attaccalite, Jean-Roch Huntzinger, Matthieu Paillet, Ahmed-Azmi Zahab, Romain Parret

Nanoscale Advances 5:1681-1690 (2023)10.1039/d2na00817c

Nanoparticle Imprint Lithography: From Nanoscale Metrology to Printable Metallic Grids

Anna Capitaine, Mehrnaz Bochet-Modaresialam, Peeranuch Poungsripong, Clémence Badie, Vasile Heresanu, Olivier Margeat, Lionel Santinacci, David Grosso, Erik Garnett, Beniamino Sciacca

ACS Nano (2023)10.1021/acsnano.3c01156

Cargo-selective and adaptive delivery of nucleic acid therapeutics by bola-amphiphilic dendrimers

Jiaxuan Chen, Dandan Zhu, Baoping Lian, Kangjie Shi, Peng Chen, Ying Li, Wenyi Lin, Ling Ding, Qiulin Long, Yang Wang, Erik Laurini, Wenjun Lan, Yun Li, Aura Tintaru, Caoyun Ju, Can Zhang, Sabrina Pricl, Juan Iovanna, Xiaoxuan Liu, Ling Peng

Proceedings of the National Academy of Sciences of the United States of America 120:e2220787120 (2023)10.1073/pnas.2220787120

Tris‐benzo[cd]indole Cyanine Enables the NIR‐photosensitized Radical and Thiol‐ene Polymerizations at 940 nm

Christine Elian, Benjamin Mourot, Camil Benbouziyane, Jean-Pierre Malval, Sonia Lajnef, Fabienne Peyrot, Florian Massuyeau, Olivier Siri, Denis Jacquemin, Simon Pascal, Davy-Louis Versace

Angewandte Chemie International Edition (2023)10.1002/anie.202305963

Enzyme-immobilized hierarchically porous covalent organic framework biocomposite for catalytic degradation of broad-range emerging pollutants in water

Nada Elmerhi, Khadega Al-Maqdi, Khawlah Athamneh, Abdul Khayum Mohammed, Tina Skorjanc, Felipe Gándara, Jesus Raya, Simon Pascal, Olivier Siri, Ali Trabolsi, Iltaf Shah, Dinesh Shetty, Syed Salman Ashraf

Journal of Hazardous Materials 459:132261 (2023)10.1016/j.jhazmat.2023.132261

Towards efficient NFA-based selective near-infrared organic photodetectors: impact of thermal annealing of polymer blends

Q. Eynaud, Y. Avalos Quiroz, T. Koganezawa, R. Sato, N. Yoshimoto, O. Margeat, C. Ruiz, J. Ackermann, Christine Videlot-Ackermann

Journal of Materials Chemistry C (2023)10.1039/D3TC01180A

Azacalixphyrin nanostructures

Daniel Ferry, Sabrina Pricl, Domenico Marson, Zhongrui Chen, Gabriel Canard, Simon Pascal, Aura Tintaru, Olivier Siri

Journal of Porphyrins and Phthalocyanines (2023)10.1142/S1088424623500785

Amphiphilic dendrimers against antibiotic resistance: light at the end of the tunnel?

Christina Galanakou, Dinesh Dhumal, Ling Peng

Biomaterials Science (2023)10.1039/D2BM01878K

Dendrimer nanosystems for adaptive tumor-assisted drug delivery via extracellular vesicle hijacking

Yifan Jiang, Zhenbin Lyu, Brigino Ralahy, Juan Liu, Tom Roussel, Ling Ding, Jingjie Tang, Artemis Kosta, Suzanne Giorgio, Richard Tomasini, Xing-Jie Liang, Nelson Dusetti, Juan Iovanna, Ling Peng

Proceedings of the National Academy of Sciences of the United States of America 120 (2023)10.1073/pnas.2215308120

Core–Shell Multiwalled Carbon Nanotube/Cobalt Corrole Hybrids for the Oxygen Reduction Reaction

Paul-Gabriel Julliard, Manel Hanana, Laurent Alvarez, Renaud Cornut, Bruno Jousselme, Gabriel Canard, Stéphane Campidelli

Energy & Fuels 37:684-692 (2023)10.1021/acs.energyfuels.2c03434

Star-shape non-fullerene acceptor featuring an aza-triangulene core for organic solar cells

Yann Kervella, José Maria Andrés Castán, Yatzil Alejandra Avalos-Quiroz, Anass Khodr, Quentin Eynaud, Tomoyuki Koganezawa, Noriyuki Yoshimoto, Olivier Margeat, Agnès Rivaton, Antonio Riquelme, Valid Mwatati Mwalukuku, Jacques Pécaut, Benjamin Grévin, Christine Videlot-Ackermann, Jörg Ackermann, Renaud Demadrille, Cyril Aumaître

Journal of Materials Chemistry C (2023)10.1039/d2tc05424h

A pH-and Metal-Actuated Molecular Shuttle in Water

Amine Kriat, Simon Pascal, Brice Kauffmann, Yann Ferrand, David Bergé-Lefranc, Didier Gigmes, Olivier Siri, Anthony Kermagoret, David Bardelang

Chemistry - A European Journal e202300633 (2023)10.1002/chem.202300633

Proton-coupled electron transfer in a pivaloyl-substituted dihydro-tetraazapentacene

Jean-François Longevial, Iryna Knysh, Shaymaa Al Shehimy, Lhoussain Khrouz, Arumugam Pandurangan, Simon Pascal, Gabriel Canard, Christophe Bucher, Denis Jacquemin, Olivier Siri

Electrochimica Acta 449:142224 (2023)10.1016/j.electacta.2023.142224

Magnetic functionalization of ZnO nanoparticles surfaces via optically generated methyl radicals

D. Marin, G. Gerbaud, O. Margeat, F. Ziarelli, F. Ferrer, O. Ouari, A. Campos, S. Bertaina, Adrien Savoyant

Journal of Chemical Physics 158:184704 (2023)10.1063/5.0152015

A Strategy to Design Substituted Tetraamino-Phenazine Dyes and Access to an NIR-Absorbing Benzoquinonediimine-Fused Quinoxaline

Tatiana Munteanu, Valérie Mazan, Mourad Elhabiri, Camil Benbouziyane, Gabriel Canard, Denis Jacquemin, Olivier Siri, Simon Pascal

Organic Letters (2023)10.1021/acs.orglett.3c01251

Deciphering electronic and structural effects in Copper Corrole/Graphene Hybrids

Kerry Wrighton-Araneda, Diego Cortés-Arriagada, Paulina Dreyse, Simon Pascal, Gabriel Canard, Luis Sanhueza

Chemistry - A European Journal (2023)10.1002/chem.202203175

2022

Hole transport layers in organic solar cells: A review

Riva Alkarsifi, Jörg Ackermann, Olivier Margeat

Journal of Metals, Materials and Minerals 32:1-22 (2022)10.55713/jmmm.v32i4.1549

Circularly polarized luminescence of encaged Eu(iii) and Tb(iii) complexes controlled by an inherently chiral remote unit

Estelle Godart, Oriane Della-Negra, Augustin Long, Alberto Insuasty, Lorenzo Arrico, Costanza Benetti, Elise Antonetti, Paola Nava, Yoann Cotelle, Nicolas Vanthuyne, Marion Jean, Simon Pascal, Jean-Pierre Dutasta, Lorenzo Di Bari, Alexandre Martinez

New Journal of Chemistry 46:20154-20159 (2022)10.1039/d2nj02360a

Fully Zwitterionic Diaminobenzoquinonediimines Promoted by Cyanoaromatic N-substituents

Tereza Horáčková, Manon H.E. Bousquet, Adrien Morice, Ugo Triballier, Gabriel Canard, Pavel Lhoták, Denis Jacquemin, Simon Pascal, Olivier Siri

Dyes and Pigments (2022)10.1016/j.dyepig.2022.110681

Thermostable ionizable lipid-like nanoparticle (iLAND) for RNAi treatment of hyperlipidemia

Bo Hu, Bo Li, Kun Li, Yuanyuan Liu, Chunhui Li, Lulu Zheng, Mengjie Zhang, Tongren Yang, Shuai Guo, Xiyu Dong, Tian Zhang, Qing Liu, Abid Hussain, Yuhua Weng, Ling Peng, Yongxiang Zhao, Xing-Jie Liang, Yuanyu Huang

Science Advances 8 (2022)10.1126/sciadv.abm1418

A biodegradable amphiphilic poly(aminoester) dendrimer for safe and effective siRNA delivery

Chi Ma, Dandan Zhu, Wenyi Lin, Ying Li, Yuanzheng Huang, Huiling Zhu, Mengyun Ye, Yang Wang, Ling Peng, Xiaoxuan Liu

Chemical Communications (2022)10.1039/D1CC06655B

Affinity driven ion exchange EG-OFET sensor for high selectivity and low limit of detection of cesium in seawater

Tin Phan Nguy, Volkan Kilinc, Ryoma Hayakawa, Catherine Henry-De-Villeneuve, Jean-Manuel Raimundo, Yutaka Wakayama, Anne Charrier

Sensors and Actuators B: Chemical 351:130956 (2022)10.1016/j.snb.2021.130956

Synthesis and Electron Accepting Properties of Two Di(benz[f]indenone)-Fused Tetraazaanthracene Isomers

Bruno Salgues, Rudraditya Sarkar, Muhammad Fajri, Yatzil Avalos-Quiroz, Anne-Doriane Manick, Michel Giorgi, Nicolas Vanthuyne, Yannick Carissan, Christine Videlot-Ackermann, Jörg Ackermann, Gabriel Canard, Jean-Luc Parrain, Boris Le Guennic, Denis Jacquemin, Muriel Amatore, Laurent Commeiras, Elena Zaborova, Fréderic Fagès

Journal of Organic Chemistry 87:3276-3285 (2022)10.1021/acs.joc.1c02942

NUPR1 protects against hyperPARylation-dependent cell death

Patricia Santofimia-Castano, Can Huang, Xi Liu, Yi Xia, Stephane Audebert, Luc Camoin, Ling Peng, Gwen Lomberk, Raul Urrutia, Philippe Soubeyran, Jose Luis Neira, Juan Iovanna

Communications Biology 5 (2022)10.1038/s42003-022-03705-1

Conjugated donor–acceptor substituted systems involving the 1,3-indandione-derived electron accepting moieties

Mark Sigalov, Royi Mazor, Arkady Ellern, Nina Larina, Vladimir Lokshin, Vladimir Khodorkovsky

RSC Advances 12:27766-27774 (2022)10.1039/d2ra05335g

Covalent organic framework based on azacalix[4]arene for the efficient capture of dialysis waste products

Tina Skorjanc, Dinesh Shetty, Felipe Gándara, Simon Pascal, Nawavi Naleem, Salma Abubakar, Liaqat Ali, Abdul Khayum Mohammed, Jesus Raya, Serdal Kirmizialtin, Olivier Siri, Ali Trabolsi

ACS Applied Materials & Interfaces (2022)10.1021/acsami.2c06841

Bola‐Amphiphilic Glycodendrimers: New Carbohydrate Mimicking Scaffolds to Target Carbohydrate‐Binding Proteins

Wenzheng Zhang, Dinesh Dhumal, Xiaolei Zhu, Brigino Ralahy, Aleksandra Ellert-Miklaszewska, Jing Wu, Erik Laurini, Yi-Wen W Yao, Chai-Lin L Kao, Juan L Iovanna, Sabrina Pricl, Bozena Kaminska, Yi Xia, Ling Peng

Chemistry - A European Journal (2022)10.1002/chem.202201400

Financement

Équipe Ackermann 1 Sources et sondes ponctuelles 2 Physique et nano-micro Ingénierie pour le Vivant 1 Équipe Peng Équipe Peng 1

  • ANR contracts

  • 1 Doc2AMU fellowship

  • 1 collaboration contract with Dracula Technologie company

  • 1 AMidex project

  • 1 "Ligue contre le Cancer" labeled team

  • 2 Horizon 2020 contracts